RT Journal Article ID 13f46c4a00442772 A1 Yanovsky, Yuri G. A1 Nikitina, E. A. A1 Nikitin, Sergey M. A1 Karnet, Yulia N. A1 Velikodny, V. Yu. T1 QUANTUM-MECHANICAL SIMULATION AND SOME EXPERIMENTAL ASSESSMENT OF THERMODYNAMICS AND MECHANISMS OF COMBUSTION OF SUSPENSION HYDROCARBON MEDIA WITH NANOSIZED HYDROCARBON ADDITIVES JF Nanoscience and Technology: An International Journal JO NST YR 2013 FD 2014-05-19 VO 4 IS 2 SP 157 OP 178 K1 quantum-mechanical simulation K1 combustion K1 hydrocarbon fuel K1 specific heat of combustion K1 reaction heat effects K1 carbon nanoparticles K1 nanotubes K1 graphene K1 graphene oxide K1 high-speed filming visualization AB Quantum-mechanical methods in the cluster approximation were used to instigate thermodynamics and mechanisms of reactions of hydrocarbon fuel combustion, in both the absence and the presence of nanosized hydrocarbon particles. As additives we considered amorphous carbon, carbon nanotubes, graphene, its multilayer modifications, and graphene oxide. The impacts of water on the combustion reaction of similar media were investigated. It was demonstrated that during combustion of water and carbon suspensions, the water molecules were disintegrated into protons and hydroxyls involved in the process of disintegration of solid hydrocarbon particles, affecting the process thermodynamics substantially. The experimental assessments of the simulation results and visualization of the processes of combustion of the said media were made using an original two-circuit unit with high-voltage ignition devices and high-speed filming technique. A qualitative matching of the theoretical predictions by the quantum-mechanical method and the observed experimental assessments was noted. PB Begell House LK https://www.dl.begellhouse.com/journals/11e12455066dab5d,3bede06f75df3d0d,13f46c4a00442772.html