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International Journal of Energetic Materials and Chemical Propulsion
ESCI SJR: 0.142 SNIP: 0.16 CiteScore™: 0.29

ISSN Imprimir: 2150-766X
ISSN On-line: 2150-7678

International Journal of Energetic Materials and Chemical Propulsion

DOI: 10.1615/IntJEnergeticMaterialsChemProp.v2.i1-6.90
pages 196-202

DISPERSION AND SELF-IGNITION CHARACTERISTICS OF BORONORGANIC COMPOUNDS BEHIND SHOCK WAVES

Boris E. Gelfand
Institute of Chemical Physics, RAS, 117977, Kosygina str.4, Moscow, Russia
S. A. Tsyganov
Semenov Institute of Chemical Physics Academy of Sciences of the USSR, Moscow, USSR, 117977
V. G. Slutskii
Semenov Institute of Chemical Physics Academy of Sciences of the USSR, Moscow, USSR, 117977
E. S. Severin
Semenov Institute of Chemical Physics Academy of Sciences of the USSR, Moscow, USSR, 117977

RESUMO

The self-ignition of dispersed boronorganic compounds and their compositions with liquid hydrocarbons has been investigated experimentally in air at T = 900−1600 К and P = 1−4 MPa. The exceptionally high chemical activity of carboranes has been revealed. The effectiveness of self-ignition promotion of carboranes with organic nitrates and halogenalkyls has been proved. The possibility of using carboranes and boralkyls as self-ignition promoters for hydrocarbons has been demonstrated.


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