Abonnement à la biblothèque: Guest
Portail numérique Bibliothèque numérique eBooks Revues Références et comptes rendus Collections
International Journal of Energetic Materials and Chemical Propulsion
ESCI SJR: 0.149 SNIP: 0.16 CiteScore™: 0.29

ISSN Imprimer: 2150-766X
ISSN En ligne: 2150-7678

International Journal of Energetic Materials and Chemical Propulsion

DOI: 10.1615/IntJEnergeticMaterialsChemProp.2014010631
pages 51-64

PREPARATION, CHARACTERIZATION, AND THERMAL BEHAVIOR OF COBALT(II) AND ZINC(II) PERCHLORATE COMPLEXES WITH N-PROPYLAMINE

Chandra Prakash Singh
Department of Chemistry, Dayanand Brajendra Swarup College (DBS) College, Kanpur 208006, India
Abhishek Singh
Department of Chemistry, Dayanand Brajendra Swarup College (DBS) College, Kanpur 208006, India

RÉSUMÉ

Two complexes of cobalt and zinc have been prepared with the molecular formula [Co(n − pa)3(ClO4)(H2O)]ClO4 and [Zn(n − pa)3(ClO4)(H2O)]ClO4, where n − pa = n-propylamine. These complexes have been characterized by elemental analysis, thermogravimetry (TG), ultraviolet/visible, and infrared spectroscopic data. The thermal properties have been investigated using TG in static air and by simultaneous TG/derivative TG/differential thermal analysis inflowing nitrogen atmosphere. The kinetics of thermolysis has been analyzed by applying model-fitting and model-free isoconversional methods using isothermal TG data recorded at five different temperatures. To observe the response of these complexes to fast heating, the explosion delay time has been recorded at various temperatures and their kinetics has been studied using these data.


Articles with similar content:

THERMOLYSIS AND THEIR KINETICS OF COPPER AND ZINC PERCHLORATE COMPLEXES WITH 2-AMINOPYRIDINE LIGAND
International Journal of Energetic Materials and Chemical Propulsion, Vol.14, 2015, issue 2
Abhishek Singh, Ashok Kumar Srivastava, Chandra Prakash Singh, Bandana Singh
BULK CATALYST FOR NITROUS OXIDE DECOMPOSITION IN SPACE THRUSTERS
International Journal of Energetic Materials and Chemical Propulsion, Vol.15, 2016, issue 2
Andre Navarro de Miranda, Sayuri Okamoto, Luis Gustavo Ferroni Pereira, Leandro José Maschio, Ricardo Vieira
PREPARATION AND CHARACTERIZATION OF Co-Cu BIMETALLIC SHAPED CATALYST SUPPORTED ON TiO2
Journal of Porous Media, Vol.20, 2017, issue 11
Moayed Hossaini Sadr, Karim Zare, Vida Nourozi Rad, Mansoor Anbia
NOVEL APPROACH TO MAKE HUGONIOT PREDICTIONS: QUANTUM MECHANICS/MOLECULAR DYNAMICS CALCULATIONS
International Journal of Energetic Materials and Chemical Propulsion, Vol.15, 2016, issue 2
Hakima Abou-Rachid, Amal Bouamoul, Mounir Jaidann, Josee Brisson
Experimental study of suspension plasma spraying of hydroxyapatite
Progress in Plasma Processing of Materials, 1997, Vol.1, 1997, issue
Etienne Bouyer, Maher I. Boulos, Francois Gitzhofer