RT Journal Article
ID 4258cbb2646985bc
A1 Tverjanovich, Andrey S.
A1 Abdrashitovh, G. O.
A1 Averyanovh, A. O.
A1 Ilyshinh, M. A.
A1 Smirnovh, A. V.
A1 Tveryanovich, Yu. S.
T1 LASER-INDUCED DECOMPOSITION OF [CO(NH3 )5 (CN5 O2 )](CLO4 )2
JF International Journal of Energetic Materials and Chemical Propulsion
JO IJEMCP
YR 2016
FD 2016-08-04
VO 15
IS 2
SP 113
OP 122
K1 NCP
K1 laser-induced dissociation
K1 coordination compound of Co
AB Dissociation of water solution of (5-nitrotetrazolato-N2)pentaaminecobalt(III) perchlorate (NCP) under laser irradiation with 355 nm wavelength was investigated by IR and Raman spectroscopy and energy-dispersive spectroscopy analysis. This light energy is in resonance with d-d transitions (1A1g → 1T2g) of Co3+ cations. Condensed products of such dissociation mainly consist of Co3 O4, CoOOH, perchlorate anions, and possibly nitrotetrazolate anions, which differ from the products at conventional thermal decomposition.
PB Begell House
LK https://www.dl.begellhouse.com/journals/17bbb47e377ce023,00cb99d9014d0006,4258cbb2646985bc.html