%0 Journal Article %A Tverjanovich, Andrey S. %A Abdrashitovh, G. O. %A Averyanovh, A. O. %A Ilyshinh, M. A. %A Smirnovh, A. V. %A Tveryanovich, Yu. S. %D 2016 %I Begell House %K NCP, laser-induced dissociation, coordination compound of Co %N 2 %P 113-122 %R 10.1615/IntJEnergeticMaterialsChemProp.2015015443 %T LASER-INDUCED DECOMPOSITION OF [CO(NH3 )5 (CN5 O2 )](CLO4 )2 %U https://www.dl.begellhouse.com/journals/17bbb47e377ce023,00cb99d9014d0006,4258cbb2646985bc.html %V 15 %X Dissociation of water solution of (5-nitrotetrazolato-N2)pentaaminecobalt(III) perchlorate (NCP) under laser irradiation with 355 nm wavelength was investigated by IR and Raman spectroscopy and energy-dispersive spectroscopy analysis. This light energy is in resonance with d-d transitions (1A1g1T2g) of Co3+ cations. Condensed products of such dissociation mainly consist of Co3 O4, CoOOH, perchlorate anions, and possibly nitrotetrazolate anions, which differ from the products at conventional thermal decomposition. %8 2016-08-04