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International Journal of Energetic Materials and Chemical Propulsion
ESCI SJR: 0.149 SNIP: 0.16 CiteScore™: 0.29

ISSN Druckformat: 2150-766X
ISSN Online: 2150-7678

International Journal of Energetic Materials and Chemical Propulsion

DOI: 10.1615/IntJEnergeticMaterialsChemProp.2012005202
pages 337-349

CATALYTIC DECOMPOSITION OF H2O2 USING FeCrAl METALLIC FOAM−BASED CATALYSTS

Rachid Amrousse
Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency (JAXA), 3-1-1 Yoshinodai, Chuo-Ku, Sagamihara, Kanagawa 252-5210, Japan
C. Augustin
Hollomet GmbH, Grunaer Weg 26, 01277 Dresden, Deutschland
K. Farhat
IC2MP, Institut de Chimie des Materiaux et des Milieux de Poitiers, 86022 Poitiers, France
Yann Batonneau
CNRS UMR 7285, IC2MP, University of Poitiers, France
Charles J. Kappenstein
Université de Poitiers, CNRS, IC2MP, Poitiers, 86073, France

ABSTRAKT

Catalysts containing 10 wt.% of Pt and MnO2 supported on coated metallic foams by γ−alumina were examined for H2O2 decomposition. Catalysts were prepared by impregnation of a high-porous γ−alumina (coating layer) surface area. Surface area measurements, SEM micrographs, and H2 chemisorption gave evidence of a uniform distribution of the active phases. Catalytic tests were performed in a batch reactor with 30 wt.% concentration of H2O2 solution. The catalytic activity, defined by temperature of ejected gas products and the pressure slopes, was higher at the beginning of the tests and decreased versus time in the case of both foam catalysts. Otherwise, MnO2-based catalyst was more active for this application.


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