%0 Journal Article
%A Tverjanovich, Andrey S.
%A Abdrashitovh, G. O.
%A Averyanovh, A. O.
%A Ilyshinh, M. A.
%A Smirnovh, A. V.
%A Tveryanovich, Yu. S.
%D 2016
%I Begell House
%K NCP, laser-induced dissociation, coordination compound of Co
%N 2
%P 113-122
%R 10.1615/IntJEnergeticMaterialsChemProp.2015015443
%T LASER-INDUCED DECOMPOSITION OF [CO(NH3 )5 (CN5 O2 )](CLO4 )2
%U https://www.dl.begellhouse.com/journals/17bbb47e377ce023,00cb99d9014d0006,4258cbb2646985bc.html
%V 15
%X Dissociation of water solution of (5-nitrotetrazolato-N2)pentaaminecobalt(III) perchlorate (NCP) under laser irradiation with 355 nm wavelength was investigated by IR and Raman spectroscopy and energy-dispersive spectroscopy analysis. This light energy is in resonance with d-d transitions (1A1g → 1T2g) of Co3+ cations. Condensed products of such dissociation mainly consist of Co3 O4, CoOOH, perchlorate anions, and possibly nitrotetrazolate anions, which differ from the products at conventional thermal decomposition.
%8 2016-08-04