PHASE EQUILIBRIA AND STRUCTURE IN THE Na3AlF6-Na2B4O7-TiO2 SYSTEM

doi:10.1615/HighTempMatProc.v4.i3.100

高温材料处理：国际期刊

总编辑s: Valiantsin M. Astashynski (open in a new tab) Andrey V. Gusarov (open in a new tab)

副主编: Nikolai N. Cherenda (open in a new tab)

每年出版 4 期

ISSN 打印: 1093-3611

ISSN 在线: 1940-4360

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PHASE EQUILIBRIA AND STRUCTURE IN THE Na₃AlF₆-Na₂B₄O₇-TiO₂SYSTEM

卷 4, 册 3, 2000, 10 pages

DOI: 10.1615/HighTempMatProc.v4.i3.100

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摘要

As part of the ternary system Na₃AlF₆-Na₂B₄O₇-TiO₂, the binary subsystem: Na₂B₄O₇-TiO₂ and the pseudobinary subsystem Na₂B₄O₇-[Na₃AlF₆-TiO₂]_e were investigated. The phase diagrams established by DTA measurements evidenced a simple eutectic point for both systems except for the concentration range > 85 wt. % Na₂B₄O₇ of the Na₂B₄O₇-[Na₃AlF₆-TiO₂]_e system where the binary paragenesis rules are no longer obeyed. Additional information regarding the structure of the mixtures were obtained by X-ray diffraction and Raman spectroscopy. Both vitreous and crystalline state were evidenced, without any new compound formation. The presence of titanium, mainly as TiO₄ tetrahedra, was also proved.

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