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传热学
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ISSN 打印: 1064-2285
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传热学

DOI: 10.1615/HeatTransRes.v39.i8.30
pages 671-684

Use of the Microscopic Properties of a Substance for a Thermodynamic Analysis of Thermal Processes

A. G. Vikulov
Moscow Aviation Institute (State Technical University), 4 Volokolamskoe Highway, Moscow, 125993, Russia

ABSTRACT

Based on the laws of quantum mechanics, a model of thermal vibrations of particles is suggested. An operator of the potential energy has been obtained for the particles that belong to different states of aggregation. In the form of the solution of the Schrödinger equation for nonelectromagnetic potential fields, a wave function that prescribes the state of particles within the limits of thermal uncertainty has been found. The relationship between the absolute temperature and the microscopic properties of elementary particles has been established. Conclusions on the correspondence of the results of quantum analysis to the classical thermodynamics laws are drawn.


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