图书馆订阅: Guest
Begell Digital Portal Begell 数字图书馆 电子图书 期刊 参考文献及会议录 研究收集
国际能源材料和化学驱动期刊
ESCI SJR: 0.149 SNIP: 0.16 CiteScore™: 0.29

ISSN 打印: 2150-766X
ISSN 在线: 2150-7678

国际能源材料和化学驱动期刊

DOI: 10.1615/IntJEnergeticMaterialsChemProp.2015011176
pages 421-436

SUPPORTED MnOx /SrO−Al2O3 HIGH-CELL DENSITY HONEYCOMB CERAMIC MONOLITH CATALYST FOR HIGH-CONCENTRATION HYDROGEN PEROXIDE DECOMPOSITION

Chuntian Wu
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
Xiaodong Wang
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
Xiunan Zhou
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
Tianzhuo Yang
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
Tao Zhang
Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology, Dalian 116024, China

ABSTRACT

High-concentration hydrogen peroxide is a potential substitute for a toxic hydrazine monopropellant. There is a pressing need for improved H2O2 decomposition catalysts to both increase bed loading and improve the resistance to a high temperature. In this paper, we describe the effects of Sr addition on the catalytic properties of MnOx/SrO−Al2O3 catalysts for high-concentration hydrogen peroxide decomposition. A structure analysis by temperature-programmed reduction and X-ray diffraction revealed that highly dispersed SrO formed on Al2O3 enhanced the dispersion and reduction capability of Mn species and facilitated the formation of more active Mn4+ species due to restraining the interaction between Mn and Al2O3 and activation of oxygen. Mn4+ species provided the main active site. The addition of Sr increased the catalytic activity and work stability of the MnOx/SrO−Al2O3 monolith catalyst.


Articles with similar content:

METHOD TO INCREASE THE ACTIVE CONTENTS OF PARTIALLY OXIDIZED BORON PARTICLES AND PERFORMANCE OF B/PB3O4 COMPOSITES WITH TREATED BORON
International Journal of Energetic Materials and Chemical Propulsion, Vol.12, 2013, issue 1
Chuan Huang, Wen Li, Yan-Chun Li, Shi Yan, Yi Cheng
ZnO-NANOPARTICLES DECORATED ON CeO2 NANORODS: AN EFFICIENT CATALYST FOR CO OXIDATION
Catalysis in Green Chemistry and Engineering, Vol.1, 2018, issue 4
Benjaram Mahipal Reddy, Damma Devaiah, Deboshree Mukherjee, Perala Venkataswamy, Muga Vithal
COMBUSTION SYNTHESIS OF ADVANCED CERAMICS, INTERMETALLICS, AND COMPOSITES
International Journal of Energetic Materials and Chemical Propulsion, Vol.10, 2011, issue 5
Chun-Liang Yeh
Oxidation of organic compounds and carbon monoixe in some molten salts and catalysts
Advances in Molten Salts, Vol.0, 1998, issue
Y. S. Chekryshkin, Z. R. Ismagilov, M. A. Kerzhentsev, Martyn G. Adamson
THERMITE-BASED COMBUSTION SYNTHESIS OF NIOBIUM SILICIDES/Al2O3 COMPOSITES
High Temperature Material Processes: An International Quarterly of High-Technology Plasma Processes, Vol.16, 2012, issue 1
Yu-Shan Huang, Chun-Liang Yeh